The Bible says that the angels (including Satan) were created long before man’s appearance..."at the ‘founding of the earth’ (they) began shouting in applause.” (Job 38:4-7)
Jesus said that "The Devil...was a manslayer when he began, and he did not stand fast in the truth, because truth is not in him." (John 8:44)
So because the Bible identified Satan as "the original serpent" (Rev. 12:9), Satan must have used the mouth of a serpent, when lying and deceiving Adam and Eve. (Genesis 2:17; 3:4)
For much more, see:
THE DEVIL - More Than Just Superstition